login to sqlpus with system account. 
sqlplus system@xe
see the present value
select dbms_xdb.gethttpport as "HTTP-Port", bms_xdb.getftpport as "FTP-Port" from dual;
--it shows  actual value. now u want to change them, use the following?
begin
   dbms_xdb.sethttpport('9999'); 
   dbms_xdb.setftpport('2100'); 
end;
/